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排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
Bowen Lv Zhaoliang Qu Baosheng Xu Yiguang Wang Daining Fang 《Ceramics International》2021,47(12):16547-16554
A numerical model is developed for surface crack propagation in brittle ceramic coatings, aiming at the intrinsic failure of rare-earth silicate environmental barrier coating systems (EBCs) under combustion conditions in advanced gas turbines. The main features of progressive degradation of EBCs in such conditions are captured, including selective silica vaporization in the top coat due to exposure to water vapor, diffusion path-dependent bond coat oxidation, as well as crack propagation during cyclic thermal loading. In light of these features, user-defined subroutines are implemented in finite element analysis, where surface crack growth is simulated by node separation. Numerical results are validated by existing experimental data, in terms of monosilicate layer thickening, thermal oxide growth, and fracture behaviors. The experimentally observed quasi-linear oxidation in the early stage is also elucidated. Furthermore, it is suggested that surface crack undergoes rapid propagation in the late stage of extended thermal cycling in water vapor and leads to catastrophic failure, driven by both thermal mismatch and oxide growth stresses. The latter is identified as the dominant mechanism of penetration. Based on detailed analyses of failure mechanisms, the optimization strategy of EBCs composition is proposed, balancing the trade-off between mechanical compliance and erosion resistance. 相似文献
32.
33.
A shale gas gathering and transportation pipeline in a good block in Sichuan Province started leaking after less than a year of operation. To investigate the causes of corrosion of the sulfate-reducing bacteria (SRB), optical microscopy, scanning electron microscopy, and X-ray diffraction were used to analyze the corrosion and perforation of the shale gas surface pipeline in conjunction with bacterial corrosion simulation experiments. The results showed that the pipeline material (L360N) conformed to the requirements of the American Petroleum Institute 5 L standard and that extracellular polymeric substances were present in the corrosion pits. The corrosion products mainly included FeCO3, FeS, CaCO3, MgCO3, and Fe mineralization. At 40°C, the uniform corrosion rate of L360N in the simulation experiment was 0.234 mm/a, and the local corrosion rate was 0.458 mm/a. SRB, saprophytes, and iron bacteria were detected in the on-site water medium and corrosion products, indicating that the main causes of shale gas pipeline corrosion are bacterial and CO2 corrosion. 相似文献
34.
Mg-Zn-Nd alloy is a promising biodegradable metal material for surgical staples during the reconstruc-tion of digestive tract due to its good biocompatibility and suitable mechanical properties.However,its deformation property and corrosion resistance should be improved to make better safety and effective-ness of staples.In the present study,bi-direction drawing was adopted to maintain the initial texture characteristics,and improve mechanical property and corrosion resistance of Mg-2Zn-0.5Nd alloy.The results showed that the microstructure after bi-direction did not change too much,but the texture could maintain its initial characteristics.The ductility of the alloy with 60 % accumulative area reduction after bi-direction drawing was increased by 70 %,indicating that an outstanding deformation property of Mg-Zn-Nd alloy can be obtained by bi-direction drawing.The corrosion resistance was also improved after bi-direction drawing compared with that under single direction drawing. 相似文献
35.
The pressure drop prediction of wet gas across single-orifice plate in horizontal pipes had been solved satisfactorily under an annular-mist flow in the upstream of orifice plates. However, this pressure drop prediction is still not clearly determined when the upstream is in an intermittent flow or stratified flow, which is corresponding to a region of low FrG (gas phase Froude number) in the flow pattern map of wet gases. In this study, the wet gas pressure drop across a single-orifice plate was experimentally investigated in the low FrG region. By the experiment, the flow pattern transition in the downstream of single-orifice plates, as well as the effects of FrG and FrL (liquid phase Froude number) on ΦG (gas phase multiplier), were determined and compared when the upstream is in the flow pattern transition and the stratified flow region, respectively. Prediction performances were examined on the available pressure drop models. It was found that no model could be capable of jointly predicting the wet gas pressure drop in the low FrG region with an acceptable accuracy. With a new method of correlating FrG and FrL simultaneously, new correlations were proposed for the low FrG region. Among which the modified Chisholm model shows the best prediction accuracies, with the prediction deviations of ΦG being within 7% and 3% when the upstream is in flow pattern transition and stratified flow region, respectively. 相似文献
36.
《Ceramics International》2022,48(20):29919-29928
MoSi2 doped Yb2Si2O7 composites were designed to extend the lifetime of Yb2Si2O7 environmental barrier coatings (EBCs) via self-healing cracks during high-temperature applications. Yb2Si2O7–Yb2SiO5–MoSi2 composites with different mass fractions were prepared by applying spark plasma sintering. X-ray diffraction results confirmed that the composites consisted of Yb2Si2O7, Yb2SiO5, and MoSi2. The thermal expansion coefficients (CTEs) of the composites increased with an increase in the MoSi2 content. The average CTE of the 15 wt% MoSi2 doped Yb2Si2O7 composite was 5.24 × 10?6 K?1, indicating that it still meets the CTE requirement of EBC materials. After being pre-cracked by using the Vickers indentation technique, the samples were annealed for 0.5 h at 1100 or 1300 °C to evaluate the crack-healing ability. Microstructural studies showed that cracks in 15 wt% MoSi2 doped Yb2Si2O7 composites were fully healed during annealing at 1300 °C. Two mechanisms may be responsible for crack healing. First, the cracks were filled with SiO2 glass formed by MoSi2 oxidation. Second, the formed SiO2 continued to react with Yb2SiO5 to form Yb2Si2O7, which can cause cracks to heal owing to volumetric expansion. The Yb2Si2O7 formation with smaller volume expansion is more beneficial. 相似文献
37.
《Ceramics International》2022,48(22):32877-32885
CaO–MgO–Al2O3–SiO2 (CMAS) deposition significantly degrades the performance of thermal barrier coatings (TBCs). In this study, the microstructure evolution of CMAS glass at temperatures below its melting point was investigated in order to study the potential influence of temperature on the applicability of CMAS glass in TBCs. The CMAS glass fabricated in this study had a melting point of 1240 °C, became opaque, and underwent self-crystallization when the temperature reached 1000 °C. After heat treatment at 1050 °C, diopside and anorthite phases precipitated from the glass; at a higher temperature (1150 °C), diopside, anorthite, and wollastonite were formed as the self-crystallization products. An increase in the dwelling time resulted in the transformation of diopside to wollastonite and anorthite. At 1250 °C, all products formed a eutectic microstructure and melted. The results indicate that even at low temperatures, CMAS glass underwent microstructure evolution, which could influence the coating surface and stress distribution when deposited on TBCs. 相似文献
38.
《Ceramics International》2022,48(18):26206-26216
Mixed oxide (MO) with localized growth feature and high growth rate remarkably affects the lifetime of thermal barrier coatings (TBCs), which indicates that clarifying the ceramic cracking mechanism induced by MO is critical for developing new coatings with high durability. Two kinds of TBC models involving spherical and layered mixed oxides are created to explore the influence of MO growth on the local stress state and crack evolution during thermal cycle. The growth of α-Al2O3 is also included in the model. The undulating interface between ceramic coat and bond coat is approximated using a cosine curve. Dynamic ceramic cracking is realized by a surface-based cohesive interaction. The ceramic delamination by simulation agrees with the experimental observation. The effects of MO coverage ratio and growth rate on the TBC failure are also discussed. The results show that the MO growth causes the local ceramic coat to bear the normal tensile stress. The failure mode of coating is turned from α-Al2O3 thickness control to MO growth control. Once the mixed oxide appears, local ceramic cracking is easy to occur. When multiple cracks connect, ceramic delamination happens. Suppressing MO formation or decreasing MO growth can evidently improve the coating durability. These results in this work can provide important theoretical guidance for the development of anti-cracking TBCs. 相似文献
39.
《Ceramics International》2022,48(2):1451-1483
Metal/ceramic composites are in high demand in several industries because of their superior thermo-mechanical properties. Among various composite types, the interpenetrating phase composites (IPCs) with percolating metallic and ceramic phases offer manifold benefits, such as a good combination of strength, toughness, and stiffness, very good thermal properties, excellent wear resistance, as well as the flexibility of microstructure and processing route selection, etc. The fabrication of metal/ceramic IPCs typically involves two steps - i) processing of an open porous ceramic body, and ii) infiltration of metallic melt in the pores to fabricate the IPC. Although significant progress has been made in recent years for developing both porous ceramics and melt infiltration methods, to the best of the knowledge of the authors, no review article summarizing all the aspects of processing and properties of IPCs has been published till date. This review article is aimed at filling this gap. Starting with a brief introduction about the current status and applications of IPCs, the various processing routes for fabricating open porous ceramic preforms and melt infiltration techniques have been discussed. Subsequently, the data available for various important physical, mechanical, and thermal properties for IPCs have been critically analyzed to thoroughly understand their dependence on various structural and processing parameters. To compare the properties of IPCs with other relevant materials, seven different Ashby material property maps have been used, and the domains for IPCs have been created in them. For each map, the concept of material indices has been employed to critically discuss how IPCs perform in relation to other material classes for various optimum design conditions. Finally, a detailed future outlook for further research on IPCs has been provided. 相似文献
40.
《Ceramics International》2022,48(4):5229-5238
The uneven growth of thermally grown oxides (TGOs) in thermal barrier coating systems is an important cause of cracking failure at the coating interface in high-temperature environments. The doping of rare earth elements in the bonding layer can effectively inhibit the formation of spinel oxides in the TGO and improve the high-temperature oxidation resistance of the coating. However, a single rare earth element has a limited effect on inhibiting TGO failure. In this study, a NiCoCrAlYHf coating was prepared using a supersonic flame spraying (HVOF) technique. The effects of HfO2 doping on the high-temperature oxidation behaviour of the coatings and diffusion behaviour of metallic elements in the coatings were investigated at 1100 °C. The results showed that the nano-sized HfO2 filled the pores between the powder particles and improved the hardness of the coating. During the high-temperature oxidation process, the oxides formed by Hf and Y had a large size and low solubility, which effectively blocked the diffusion of Al. This slowed the generation of spinel oxides, effectively inhibited the growth of the TGO, it inhibits the initiation and propagation of cracks within the coating, reduces damage to the coating from tensile and compressive stresses at the interface, and improved the high-temperature oxidation resistance of the coating. 相似文献